Hello, hirak99, and welcome to TST
100C is way too hot and risks damage to your processor. I am very surprised that it didn't go into automatic shutdown with that temperature, which processors are designed to do to try and prevent damage to them.
Seeing as your case is a full ATX sized one, you should have a space for at least one fan at the front as well. Ideally what you want is to put a fan in the front and in the back of the same size (two of the same brand/model would be good as it means you aren't taking more out than you're putting in and vice versa) to get some air moving through the case. I personally highly recommend
Sharkoon fans as they are virtually silent and move more air than a regular fan spinning at the same RPM.
Also I would recommend getting a
Zalman fan for your processor and some Arctic Silver thermal paste to use with it. Zalman fans normally come with a manual speed adjuster so you can turn it up when you have your game open to cool it more. I have mine pretty much turned all the way down for normal use, and it stays around the mid 30's. As I type this my CPU is 34C, which is a perfectly fine temp at low usage. It also barely changes when I watch videos etc.
I hope this is of some help, please let me know if you would like any more information